EMULSION LIQUID MEMBRANE EXTRACTION OF CERIUM IONS FROM ACIDIC SOLUTION USING CYANEX 301

Aziza Hattou, Dahia Meridja, Shadia M. Sirry, Kamel Belhamel

Abstract


 Membrane processes for separation of chemical species from a mixture are gaining in importance and are emerging as a viable alternative to conventional separation processes. The emulsion liquid membrane (ELM) technique was regarded as an emerging separation technology and was extensively examined for potential applications in such fields as hydrometallurgy, environmental engineering, biochemical engineering, pharmaceutical engineering, and food technology.

In the present work, the removal of Cerium ions from acidic solution by using an emulsion liquid membrane (ELM) technique was investigated and we obtained > 98% efficiency with the treatment. For the transport of Ce(III) ions  using Cyanex 301  as extractant, the effects of extractant and surfactant concentrations, mixing speed, concentration and type of stripping solution, phase ratio, treatment ratio, and nature of diluent on the extraction rate were studies. Under the optimum conditions, solvent extraction and stripping of Ce(III) ions were investigated.


Keywords


Cerium(III) ion; emulsion liquid membrane;Selectivity; extractant; cyanex 301

Full Text:

PDF PDF

References


Vladimir S. Kislik, Liquid membranes, Principles and applications in chemical separation and wastewater treatment, Elseiver, 1st edition, UK, 2010.

Valenzuela, F., Cabrera, J., Basualto, C. and Hagar, J. S. (2005). Kinetics of copper removal from acidic mine drainage by a liquid emulsion membrane. Miner. Eng., 18, 1224-32.

Othman, N., Mat, H. and Goto, M. (2006). Separation of silver from photographic wastes by emulsion liquid membrane system. J. Membr. Sci., 282, 171-7.

Hou H L, Wang Y D, Xu J H, Chen J N. Solvent extraction of La(III) with 2-ethylhexyl phosphoric acid-2-ethylhexyl ester (EHEHPA) by membrane dispersion micro-extractor. J. Rare Earths, 2013. 31(11): 1114.

Ambare D N, Ansari S A, Anitha M, Kandwal P, Singh DK, Singh H, Mohapatra P K. Non-dispersive solvent extraction of neodymium using a hollow fiber contactor:Mass transfer and modeling studies. J. Membr. Sci., 2013,446: 106.

Sun X Q, Peng B, Ji Y, Chen J, Li D Q. The solid–liquid extraction of yttrium from rare earths by solvent (ionic liquid) impreganated resin coupled with complexing method. Sep. Purif. Technol., 2008, 63(1): 61.

Sun X Q, Ji Y, Chen J, Ma J T. Solvent impregnated resin prepared using task-specific ionic liquids for rare earth separation. J. Rare Earths, 2009, 27(6): 932.

Lee G S, Uchikoshi M, Mimura K, Isshiki M. Separation of major impurities Ce, Pr, Nd, Sm, Al, Ca, Fe, and Zn from La using bis(2-ethylhexyl)phosphoric acid (D2EHPA)-impregnated resin in a hydrochloric acid medium. Sep. Purif. Technol., 2010, 71(2): 186.

Yadav K K, Singh D K, Anitha M, Varshney L, Singh H. Studies on separation of rare earths from aqueous media by polyethersulfone beads containing D2EHPA as extractant. Sep. Purif. Technol., 2013, 118(0): 350.

Deng Y F, Zhao H, Chen J, Li Y M, Liu W F. Ionic liquids as novel spectroscopic solvents for Eu(III)-containing complex. J. Rare Earths, 2011, 29(10): 915.

Sun X Q, Ji Y, Guo L, Chen J, Li D Q. A novel ammonium ionic liquid based extraction strategy for separating scandium from yttrium and lanthanides. Sep. Purif. Technol., 2011, 81(1): 25.

Liu Y H, Chen J, Li D Q. Application and perspective of ionic liquids on rare earths green separation. Sep. Purif. Technol., 2012, 47(2SI): 223.

Turanov A N, Karandashev V K, Baulin V E. Extraction of lanthanides(III) with N,N'-bis(diphenylphosphinyl-methylcarbonyl)diaza-18-crown-6 in the presence of ionic liquids. Solvent Extr. Ion Exc., 2012, 30(3): 244.

Ngomsik A F, Bee A, Talbot D, Cote G. Magnetic solidliquid extraction of Eu(III), La(III), Ni(II) and Co(II) with maghemite nanoparticles. Sep. Purif. Technol., 2012, 86(0):1.

Zhang L, Ding S D, Yang T, Zheng G C. Adsorption behavior of rare earth elements using polyethyleneglycol (phosphomolybdate and tungstate) heteropolyacid sorbents in nitric solution. Hydrometallurgy, 2009, 99(1-2): 109.

Bartsch R.A., Way J. (Eds.), Chemical Separation with Liquid Membranes, ACS Symposium Series 642, American Chemical Society, Washington, DC, 1996.

Nakashio F., Recent advances in separation of metals by liquid surfactant membranes, J. Chem. Eng. Jpn. 26: 123–133 (1993).

Marr R., Kopp A., Liquid membrane technology-survey of phenomena, mechanisms and models, Int. Chem. Eng. 22: 44–60 (1982).

Mikucki B., Metal extraction with liquid surfactant membranes: the role of the emulsifying agent, M.Sc. Thesis, The Pennsylvania State University, 1984.

Kumbasar R.A., Extraction and concentration of cobalt from acidic leach solutions containing Co–Ni by emulsion liquid membrane using TOA as extractant, Journal of Industrial and Engineering Chemistry 16: 448-454 (2010).

Kumbasar R.A., Transport of cadmium ions from zinc plant leach solutions through emulsion liquid membrane-containing Aliquat 336 as carrier, Separation and Purification Technology 63: 592–599 (2008).


Refbacks

  • There are currently no refbacks.




Copyright (c) 2015 ALGERIAN JOURNAL OF NATURAL PRODUCTS

_________________________________________________________________________________________________________________________

 All open access articles published in AJNP are distributed under the terms of the  Creative Commons Attribution-  4.0 International License

The research works published in this journal are free to be accessed. They can be shared (copied and redistributed in any medium or format) and\or adapted (remixed, transformed, and built upon the material for any purpose, commercially and\or not commercially) under the following terms: attribution (appropriate credit must be given indicating original authors, research work name and publication name mentioning if changes were made) and without adding additional restrictions (without restricting others from doing anything the actual license permits). Authors retain the full copyright of their published research works and cannot revoke these freedoms as long as the license terms are followed.

 

 Flag Counter